Issue 40, 2013
From the journal:

RSC Advances

Hetero Diels–Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C†

Santosh J. Gharpure,‡*ab   A. M. Sathiyanarayanana  and  Prasanna K. Vurama  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Madras, Chennai – 600036, Tamil Nadu, India

b Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai – 400076, India
E-mail: sjgharpure@iitb.ac.in
Fax: (+91)-22 2576 7152
Tel: (+91)-22 2576 7171

Abstract

Hetero Diels–Alder reaction of olefin with o-quinone methides (o-QMs) generated using (±)-binolphosphoric acid was developed for the stereoselective synthesis of 2,4-diarylbenzopyrans. The method thus developed was utilized in the formal synthesis of myristinin B/C.

Graphical abstract: Hetero Diels–Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C

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Article information

DOI
https://doi.org/10.1039/C3RA43526A
Article type
Communication
Submitted
10 Jul 2013
Accepted
05 Aug 2013
First published
07 Aug 2013

RSC Adv., 2013,3, 18279-18282

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Hetero Diels–Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C

S. J. Gharpure, A. M. Sathiyanarayanan and P. K. Vuram, RSC Adv., 2013, 3, 18279 DOI: 10.1039/C3RA43526A

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