Issue 26, 2013
From the journal:

Organic & Biomolecular Chemistry

Taming furfurylcations for the synthesis of privileged structures and novel scaffolds†‡

Seema Dhimana  and  S. S. V. Ramasastry*a  

* Corresponding authors

a Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, S A S Nagar, Manuali 140 306, Punjab, India
E-mail: ramsastry@iisermohali.ac.in
Fax: +91 172 2240266
Tel: +991 172 2240266

Abstract

Furfuryl cations are generated via a highly efficient bismuth-catalyzed reaction of furfuryl alcohols. This systematic study provides insight on the reactivity profile of furfuryl cations towards nucleophilic substitution reactions. Novel C–C, C–N, C–O and C–S bond forming reactions of furfuryl cations have been developed, thus providing access to a diverse array of building blocks for further manipulations.

Graphical abstract: Taming furfuryl cations for the synthesis of privileged structures and novel scaffolds

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Article information

DOI
https://doi.org/10.1039/C3OB40814K
Article type
Communication
Submitted
23 Apr 2013
Accepted
17 May 2013
First published
20 May 2013

Org. Biomol. Chem., 2013,11, 4299-4303

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Taming furfuryl cations for the synthesis of privileged structures and novel scaffolds

S. Dhiman and S. S. V. Ramasastry, Org. Biomol. Chem., 2013, 11, 4299 DOI: 10.1039/C3OB40814K

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