Issue 1, 2013
From the journal:

Green Chemistry

Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds†

Percia B. Arockiam,a   Cédric Fischmeister,a   Christian Bruneau*a  and  Pierre H. Dixneuf*a  

* Corresponding authors

a Centre of Catalysis and Green Chemistry, OMC-Institut Sciences Chimiques de Rennes, UMR 6226: CNRS-Université de Rennes, Campus de Beaulieu, 35042 Rennes, France
E-mail: christian.bruneau@univ-rennes1.fr, pierre.dixneuf@univ-rennes1.fr

Abstract

The ruthenium(II)-phosphine catalyst RuCl2(PPh3)(p-cymene) operating water selectively leads to ortho monoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc)2(p-cymene) in water produces mixed bifunctional derivatives.

Graphical abstract: Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

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Article information

DOI
https://doi.org/10.1039/C2GC36222H
Article type
Communication
Submitted
02 Aug 2012
Accepted
28 Sep 2012
First published
01 Oct 2012

Green Chem., 2013,15, 67-71

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Ruthenium(II)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

P. B. Arockiam, C. Fischmeister, C. Bruneau and P. H. Dixneuf, Green Chem., 2013, 15, 67 DOI: 10.1039/C2GC36222H

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