Dehydrogenative desulfurization of thiourea derivatives to give carbodiimides, using hydrosilane and an iron complex†
Abstract
Dehydrogenative desulfurization of thiourea derivatives (RNHC(S)NHR′) has been achieved, to give C
NR′), in the reaction with hydrosilane and (η5-C5H5)Fe(CO)2Me. The obtained