Stable and high-rate overcharge protection for rechargeable lithium batteries

Abstract

Rechargeable lithium or lithium-ion cells can be overcharge-protected by an electroactive polymer composite separator. The use of non-woven fibrous membranes instead of conventional microporous membranes as the composite substrates allowed better distribution of the electroactive polymer, which led to improved utilization and a 40-fold increase in sustainable current density. For the first time, stable overcharge protection for hundreds of cycles was demonstrated in several cell chemistries, including LiNi_1/3Co_1/3Mn_1/3O₂, LiFePO₄, and spinel Li_1.05Mn_1.95O₄ half-cells. Protection at a charging rate as high as 5 C was achieved at a steady state cell potential below 4.85 V.