Issue 31, 2013
From the journal:

CrystEngComm

A new copper chloride chain by supported hydrogen bonding†

Matti Tuikka,a   Ülo Kersenb  and  Matti Haukka*c  

* Corresponding authors

a Department of Chemistry, University of Jyväskylä, P.O. Box 35, FI-40014, Finland
E-mail: matti.tuikka@jyu.fi

b School of Chemical Technology, Aalto University, FI-00076 Aalto, Finland
E-mail: ukersen@hotmail.com

c Department of Chemistry, University of Jyväskylä, P.O. Box 35, FI-40014, Finland
E-mail: matti.o.haukka@jyu.fi

Abstract

In the current paper we introduce a new type of Cu–Cl polymer ([H2bipip]2+[CuCl3]2−)n. In this polymer the trigonal CuCl3 units are covalently linked via chloride bridges. The structure is supported by the bipiperidinium cation ([H2bipip]2+) via hydrogen bonds. The cation plays an essential role in formation of the polymeric structure. The closely related piperazinium (H2pip)2+ cation also leads to a hydrogen bonded assembly of CuCl3 ([H2pip]2+[CuCl3]2−), but a covalently bound polymer was not obtained.

Graphical abstract: A new copper chloride chain by supported hydrogen bonding

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CE40692J
Article type
Paper
Submitted
22 Apr 2013
Accepted
24 May 2013
First published
27 Jun 2013

CrystEngComm, 2013,15, 6177-6183

Permissions

Request permissions

A new copper chloride chain by supported hydrogen bonding

M. Tuikka, Ü. Kersen and M. Haukka, CrystEngComm, 2013, 15, 6177 DOI: 10.1039/C3CE40692J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements