Issue 84, 2013

Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

Abstract

A novel catalytic cross deoxygenative and dehydrogenative coupling reaction of aldehydes and alkenes was established via a cooperative catalysis approach. This transformation provided an efficient and atom-economic protocol for the synthesis of 1,4-skipped dienes from aldehydes and simple alkenes under oxidant-free reaction conditions.

Graphical abstract: Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

Supplementary files

Article information

Article type
Communication
Submitted
18 Jul 2013
Accepted
26 Aug 2013
First published
29 Aug 2013

Chem. Commun., 2013,49, 9839-9841

Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

B. Qian, G. Zhang, Y. Ding and H. Huang, Chem. Commun., 2013, 49, 9839 DOI: 10.1039/C3CC45428B

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