Issue 69, 2013
From the journal:

Chemical Communications

A spin-crossover ionic liquid from the cationic iron(iii) Schiff base complex†

Megumi Okuhata,a   Yusuke Funasako,a   Kazuyuki Takahashia  and  Tomoyuki Mochida*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, Rokkodai, Nada, Hyogo 657-8501, Japan
E-mail: tmochida@platinum.kobe-u.ac.jp
Fax: +81-78-803-5679

Abstract

A thermochromic magnetic ionic liquid containing a cationic iron(III) Schiff-base complex has been developed, whose color and magnetic moment change with temperature because of spin crossover in the liquid state. This spin-crossover behavior closely resembles that of a solid having the same cation.

Graphical abstract: A spin-crossover ionic liquid from the cationic iron(iii) Schiff base complex

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Article information

DOI
https://doi.org/10.1039/C3CC44199G
Article type
Communication
Submitted
04 Jun 2013
Accepted
01 Jul 2013
First published
01 Jul 2013

Chem. Commun., 2013,49, 7662-7664

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A spin-crossover ionic liquid from the cationic iron(III) Schiff base complex

M. Okuhata, Y. Funasako, K. Takahashi and T. Mochida, Chem. Commun., 2013, 49, 7662 DOI: 10.1039/C3CC44199G

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