Issue 62, 2013
From the journal:

Chemical Communications

Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions†

Olga Ekkert,a   Ottmar Tuschewitzki,a   Constantin G. Daniliuc,‡a   Gerald Kehra  and  Gerhard Erker*a  

* Corresponding authors

a Organisch-Chemisches Institut, Universität Münster, Corrensstraße 40, D-48149 Münster, Germany
E-mail: erker@uni-muenster.de
Fax: +49-251-83 36503

Abstract

Simple alkenylbis(pentafluorophenyl)boranes undergo 1,1-alkenylboration with phosphanylacetylenes to give phosphane–borane Lewis pairs with a conjugated diene backbone.

Graphical abstract: Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

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Article information

DOI
https://doi.org/10.1039/C3CC43294G
Article type
Communication
Submitted
03 May 2013
Accepted
11 Jun 2013
First published
12 Jun 2013

Chem. Commun., 2013,49, 6992-6994

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Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions

O. Ekkert, O. Tuschewitzki, C. G. Daniliuc, G. Kehr and G. Erker, Chem. Commun., 2013, 49, 6992 DOI: 10.1039/C3CC43294G

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