Issue 59, 2013
From the journal:

Chemical Communications

First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers†

Yogesh Patil,a   Hisao Hori,b   Hirotaka Tanaka,b   Takehiko Sakamotob  and  Bruno Ameduri*a  

* Corresponding authors

a Ingénierie et Architectures Macromoléculaires, Institut Charles Gerhardt UMR 5253, 8, rue de l'École Normale, 34296 Montpellier Cedex1, France
E-mail: bruno.ameduri@enscm.fr

b Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka 259-1293, Japan

Abstract

The radical homopolymerisation of 2-trifluoromethacrylic acid (MAF) initiated by Na2S2O8 in water, under the influence of pH, led to original water soluble surfactants, the decomposition of which was investigated. The value of the square of the propagation rate constant to the termination rate constant, kp2/kte, of MAF was 4 × 10−3 l mol−1 s−1 at 80 °C.

Graphical abstract: First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers

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Article information

DOI
https://doi.org/10.1039/C3CC42395F
Article type
Communication
Submitted
02 Apr 2013
Accepted
24 May 2013
First published
28 May 2013

Chem. Commun., 2013,49, 6662-6664

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First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers

Y. Patil, H. Hori, H. Tanaka, T. Sakamoto and B. Ameduri, Chem. Commun., 2013, 49, 6662 DOI: 10.1039/C3CC42395F

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