Issue 41, 2013
From the journal:

Chemical Communications

Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations†

Matthew Purzycki,a   Wang Liu,a   Göran Hilmersson*b  and  Fraser F. Fleming*a  

* Corresponding authors

a Department of Chemistry, Duquesne University, 600 Forbes Ave, Pittsburgh, USA
E-mail: flemingf@duq.edu
Fax: +1 412 396 5683
Tel: +1 412 396 6031

b Department of Chemistry, Göteborg University, Göteborg, Sweden
E-mail: hilmers@chem.gu.se
Tel: +46 (0)31 786 90 22

Abstract

13C NMR analyses of a series of metalated arylacetonitriles and cyclohexanecarbonitriles with the synthetically relevant metals Li, Mg, and Cu identifies the influence of the carbon scaffold and the nature of the metal on the preference for N- or C-metalation.

Graphical abstract: Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

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Article information

DOI
https://doi.org/10.1039/C3CC41703D
Article type
Communication
Submitted
06 Mar 2013
Accepted
04 Apr 2013
First published
15 Apr 2013

Chem. Commun., 2013,49, 4700-4702

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Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu cations

M. Purzycki, W. Liu, G. Hilmersson and F. F. Fleming, Chem. Commun., 2013, 49, 4700 DOI: 10.1039/C3CC41703D

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