Issue 45, 2013
From the journal:

Chemical Communications

Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(ii)†

Holger Braunschweig*a  and  Alexander Dammea  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

cis-[(Cy3P)2Pt{B(OMe)2}2] (1) was obtained in quantitative yield and fully characterised. The thermal stability of 1 was investigated in solution using multinuclear NMR spectroscopy revealing a hitherto unknown temperature-dependent equilibrium between 1 and the corresponding starting materials [Pt(PCy3)2] and free B2(OMe)4.

Graphical abstract: Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(ii)

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Article information

DOI
https://doi.org/10.1039/C3CC41444B
Article type
Communication
Submitted
25 Feb 2013
Accepted
08 Apr 2013
First published
08 Apr 2013

Chem. Commun., 2013,49, 5216-5218

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Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

H. Braunschweig and A. Damme, Chem. Commun., 2013, 49, 5216 DOI: 10.1039/C3CC41444B

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