Issue 9, 2013
From the journal:

Chemical Communications

A sandwich-type phthalocyaninato metal sextuple-decker complex: synthesis and NLO properties†

Hailong Wang,a   Dongdong Qi,a   Zheng Xie,b   Wei Cao,a   Kang Wang,a   Hong Shanga  and  Jianzhuang Jiang*a  

* Corresponding authors

a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn
Fax: +86 10-6233-2462
Tel: +86 10-6233-2592

b Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Science, Beijing 100190, China

Abstract

A hexakis[2,3,9,10,16,17,23,24-octa(butyloxy)phthalocyaninato] samarium(III)–cadmium(II) sextuple-decker complex (Pc*)Sm(Pc*)Cd(Pc*)Cd(Pc*)Cd(Pc*)Sm(Pc*) (1) with six phthalocyanine ligands bridged by two samarium(III) and three cadmium(II) ions, representing the largest stacked tetrapyrrole metal molecule in the sandwich series in terms of the tetrapyrrole-deck number, has been synthesized and characterized spectroscopically and electrochemically. Investigation of the nonlinear optical properties reveals the excellent optical limiting property of this compound.

Graphical abstract: A sandwich-type phthalocyaninato metal sextuple-decker complex: synthesis and NLO properties

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Article information

DOI
https://doi.org/10.1039/C2CC38088A
Article type
Communication
Submitted
08 Nov 2012
Accepted
10 Dec 2012
First published
11 Dec 2012

Chem. Commun., 2013,49, 889-891

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A sandwich-type phthalocyaninato metal sextuple-decker complex: synthesis and NLO properties

H. Wang, D. Qi, Z. Xie, W. Cao, K. Wang, H. Shang and J. Jiang, Chem. Commun., 2013, 49, 889 DOI: 10.1039/C2CC38088A

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