Issue 15, 2013
From the journal:

Analyst

Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes†

Manzar Sohail,a   Roland De Marco,*ab   Muhammad Tanzirul Alam,a   Marcin Pawlakc  and  Eric Bakkerc  

* Corresponding authors

a Faculty of Science, Health, Education and Engineering, University of the Sunshine Coast, 90 Sippy Downs Drive, Sippy Downs, Queensland 4556, Australia
E-mail: rdemarc1@usc.edu.au
Fax: +61 7 5456 5544
Tel: +61 7 5430 2867

b Department of Chemistry, Curtin University, GPO Box U1987, Perth, Western Australia 6109, Australia

c Department of Inorganic and Analytical Chemistry, University of Geneva, Quai Ernest-Ansermet 30, CH-1211 Geneva, Switzerland

Abstract

Cyclic voltammetry (CV), synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and near edge X-ray absorption fine structure (NEXAFS) show that oxidation of ferrocene tagged PVC induces an accumulation of high molecular weight polymer at the buried interface between the substrate electrode and the plasticized membrane.

Graphical abstract: Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes

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Article information

DOI
https://doi.org/10.1039/C3AN00464C
Article type
Communication
Submitted
07 Mar 2013
Accepted
17 May 2013
First published
17 May 2013

Analyst, 2013,138, 4266-4269

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Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes

M. Sohail, R. De Marco, M. T. Alam, M. Pawlak and E. Bakker, Analyst, 2013, 138, 4266 DOI: 10.1039/C3AN00464C

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