Organotemplate-free and one-pot fabrication of nano-rod assembled plate-like micro-sized mordenite crystals

Limin Ren; Qiang Guo; Haiyan Zhang; Longfeng Zhu; Chengguang Yang; Liang Wang; Xiangju Meng; Zhaochi Feng; Can Li; Feng-Shou Xiao

doi:10.1039/C2JM30478C

Organotemplate-free and one-pot fabrication of nano-rod assembled plate-like micro-sized mordenite crystals†

Limin Ren,^b Qiang Guo,^c Haiyan Zhang,^b Longfeng Zhu,^b Chengguang Yang,^b Liang Wang,^b Xiangju Meng,^a Zhaochi Feng,^c Can Li^c and Feng-Shou Xiao*^a

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* Corresponding authors

^a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University (XiXi Campus), Hangzhou, China
E-mail: fsxiao@zju.edu.cn

^b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, China

^c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

Abstract

Plate-like micro-sized MOR and Fe-MOR zeolite crystals assembled from highly uniform nano-rods are successfully fabricated by an organotemplate-free method during one-pot crystallization in the presence of a MOR seed solution. The seed solution rich in 4-membered rings plays a critical role for the formation of the unique nano-rod assembled structure.

Journal of Materials Chemistry

Organotemplate-free and one-pot fabrication of nano-rod assembled plate-like micro-sized mordenite crystals†

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Organotemplate-free and one-pot fabrication of nano-rod assembled plate-like micro-sized mordenite crystals

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