Issue 10, 2012
From the journal:

CrystEngComm

Supramolecular architecture of silver(I) coordination polymers containing polydentate N-donor ligands†

Kittipong Chainok,ab   Suzanne M. Neville,a   Craig M. Forsyth,a   William J. Gee,a   Keith S. Murraya  and  Stuart R. Batten*a  

* Corresponding authors

a School of Chemistry, Monash University, Building 23, Clayton, Victoria, Australia
E-mail: stuart.batten@monash.edu
Fax: +61 3 9905 4597

b School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand

Abstract

The reaction of the polydentate N-donor ligands bmtz, H2bmtz, and bptz with various silver salts was investigated. New 1D coordination polymers [Ag2(bmtz) (ClO4)]ClO4 (1), [Ag(bmtz)]ClO4·MeCN (2), [{Ag(tcm)}2(H2bmtz)(MeCN)] (3) and [Ag(bptz)(NO3)] (5), and 2-D sheet structures, [{Ag(tcm)}2bmtz] (4), were synthesized. The structures are built up through the combination of coordination bonds, hydrogen bonding, Ag–π, π–π, and anion–π interactions to generate new supramolecular architectures. The supramolecular structure of the protonated amine salt [H2bptz](NO3)2 (6) is also described.

Graphical abstract: Supramolecular architecture of silver(I) coordination polymers containing polydentate N-donor ligands

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Article information

DOI
https://doi.org/10.1039/C2CE25225B
Article type
Paper
Submitted
04 Dec 2011
Accepted
06 Mar 2012
First published
30 Mar 2012

CrystEngComm, 2012,14, 3717-3726

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Supramolecular architecture of silver(I) coordination polymers containing polydentate N-donor ligands

K. Chainok, S. M. Neville, C. M. Forsyth, W. J. Gee, K. S. Murray and S. R. Batten, CrystEngComm, 2012, 14, 3717 DOI: 10.1039/C2CE25225B

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