Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal–organic frameworks (M = Ca, Sr and Ba)

Jesús Ferrando-Soria; Marcus T. M. Rood; Miguel Julve; Francesc Lloret; Yves Journaux; Jorge Pasán; Catalina Ruiz-Pérez; Oscar Fabelo; Emilio Pardo

doi:10.1039/C1CE06203D

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Influence of the alkaline earth cations on the topology of M^II/Cu^II mixed-metal–organic frameworks (M = Ca, Sr and Ba)†

Jesús Ferrando-Soria,^a Marcus T. M. Rood,^a Miguel Julve,^a Francesc Lloret,*^a Yves Journaux,^b Jorge Pasán,^c Catalina Ruiz-Pérez,^c Oscar Fabelo^cde and Emilio Pardo*^a

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* Corresponding authors

^a Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, València, Spain
E-mail: Francisco.Lloret@uv.es, Emilio.Pardo@uv.es
Fax: +343544322
Tel: +343544442

^b Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, UMR 7201, Paris, France

^c Laboratorio de Rayos X y Materiales Moleculares, Departamento de Fisica Fundamental I, Universidad de La Laguna, Tenerife, Spain

^d Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Zaragoza, Spain

^e Institut Laue-Langevin, 6, rue Jules Horowitz BP 156, Grenoble Cedex 9, France

Abstract

The use of the mononuclear copper(II) complex, [Cu^II(Me₂pma)₂]²⁻ (Me₂pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square–octagonal [Ca^II₂Cu^II₃] or square [M^II₂Cu^II₃] (M = Sr and Ba) layered structures of (4·8²) and (4⁴·6²) net topologies, respectively.

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Article information

DOI: https://doi.org/10.1039/C1CE06203D
Article type: Communication
Submitted: 14 Sep 2011
Accepted: 15 Nov 2011
First published: 12 Dec 2011

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CrystEngComm, 2012,14, 761-764

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Influence of the alkaline earth cations on the topology of M^II/Cu^II mixed-metal–organic frameworks (M = Ca, Sr and Ba)

J. Ferrando-Soria, M. T. M. Rood, M. Julve, F. Lloret, Y. Journaux, J. Pasán, C. Ruiz-Pérez, O. Fabelo and E. Pardo, CrystEngComm, 2012, 14, 761 DOI: 10.1039/C1CE06203D

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