Issue 84, 2012

σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and Pbii fragments

Abstract

Mono- and diplatinum plumbylene complexes are prepared in which the bonding comprises synergic σ donation between the Pt and Pb atoms. The bonding distinguishes the complexes from both the classical Fischer carbene bonding model and M→Pb dative-only bonding. The Pt–Pb bond of the monoplatinum complex is stable, while the diplatinum complex reversibly loses one Pt fragment.

Graphical abstract: σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and Pbii fragments

Supplementary files

Article information

Article type
Communication
Submitted
09 Aug 2012
Accepted
04 Sep 2012
First published
05 Sep 2012

Chem. Commun., 2012,48, 10410-10412

σ-Donor–σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt0 and PbII fragments

H. Braunschweig, A. Damme, R. D. Dewhurst, F. Hupp, J. O. C. Jimenez-Halla and K. Radacki, Chem. Commun., 2012, 48, 10410 DOI: 10.1039/C2CC35777A

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