Issue 67, 2012

Room temperature reversible C–H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation viasolvent activation

Abstract

Room temperature reversible C–H activation mediated by a designed diphosphine platinum complex is presented. These findings are demonstrated through mechanistic studies involving kinetics, isotopic effects, and corroborated by DFT calculations. The coupling between two unactivated aromatic derivatives is also demonstrated.

Graphical abstract: Room temperature reversible C–H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation

Supplementary files

Article information

Article type
Communication
Submitted
29 May 2012
Accepted
29 Jun 2012
First published
29 Jun 2012

Chem. Commun., 2012,48, 8350-8352

Room temperature reversible C–H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation

E. Nicolas, X. le Goff, S. Bouchonnet and N. Mézailles, Chem. Commun., 2012, 48, 8350 DOI: 10.1039/C2CC33847E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements