Evidence for magnetic anisotropy of [NbIV(CN)8]4− in a pillared-layered Mn2Nb framework showing spin-flop transition

Dawid Pinkowicz; Michał Rams; Wojciech Nitek; Bernard Czarnecki; Barbara Sieklucka

doi:10.1039/C2CC32234J

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Evidence for magnetic anisotropy of [Nb^IV(CN)₈]⁴⁻ in a pillared-layered Mn₂Nb framework showing spin-flop transition†

Dawid Pinkowicz,*^a Michał Rams,^b Wojciech Nitek,^a Bernard Czarnecki^a and Barbara Sieklucka^a

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* Corresponding authors

^a Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland
E-mail: pinkowic@chemia.uj.edu.pl, http://www.chemia.uj.edu.pl/znmm/index-en.html

^b Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków, Poland

Abstract

The first example of the [Nb(CN)₈]-based pillared-layered-type framework system {[Mn^II₂(bpdo)(H₂O)₄][Nb^IV(CN)₈]·6H₂O}_n (bpdo = 4,4′-bipyridyl-N,N′-dioxide) has been obtained and characterized structurally and magnetically. The presented results provide the first evidence for substantial magnetic anisotropy of [Nb^IV(CN)₈].

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Article information

DOI: https://doi.org/10.1039/C2CC32234J
Article type: Communication
Submitted: 27 Mar 2012
Accepted: 17 Apr 2012
First published: 18 Apr 2012

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Chem. Commun., 2012,48, 8323-8325

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Evidence for magnetic anisotropy of [Nb^IV(CN)₈]⁴⁻ in a pillared-layered Mn₂Nb framework showing spin-flop transition

D. Pinkowicz, M. Rams, W. Nitek, B. Czarnecki and B. Sieklucka, Chem. Commun., 2012, 48, 8323 DOI: 10.1039/C2CC32234J

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