Issue 19, 2012
From the journal:

Chemical Communications

Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms†‡

Juan Alberto Sirvent,a   Francisco Foubelo*a  and  Miguel Yus*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias and Instituto de Síntesis Orgánica (ISO), Universidad de Alicante, Apdo. 99, 03080 Alicante, Spain
E-mail: foubelo@ua.es, yus@ua.es

Abstract

Indium-mediated allylation of N-tert-butanesulfinyl ketimines afforded in high yields and diastereoselectivities homoallylic amine derivatives with the nitrogen atom bonded to a quaternary stereocenter.

Graphical abstract: Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC17493F
Article type
Communication
Submitted
30 Nov 2011
Accepted
11 Jan 2012
First published
12 Jan 2012

Chem. Commun., 2012,48, 2543-2545

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Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

J. A. Sirvent, F. Foubelo and M. Yus, Chem. Commun., 2012, 48, 2543 DOI: 10.1039/C2CC17493F

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