Issue 12, 2012
From the journal:

Green Chemistry

pH-switched HRP-catalyzed dimerization of resveratrol: a selective biomimetic synthesis†

Chang Li,a   Jing Lu,a   Xiaofei Xu,a   Ruilin Hua  and  Yuanjiang Pan*a  

* Corresponding authors

a Department of Chemistry, Zhejiang University, Hangzhou, P.R. China
E-mail: panyuanjiang@zju.edu.cn
Fax: +86 571 87951629
Tel: +86 571 87951629

Abstract

A selective, concise and green biomimetic synthesis strategy of seven resveratrol dimers from natural resveratrol monomer as starting material is described. By succinct adjustment of environmental pH, the enzyme used, horseradish peroxidase (HRP), can perform in three distinctly different patterns and five dimers form with considerable selectivity. Two other derivative dimers are subsequently synthesized.

Graphical abstract: pH-switched HRP-catalyzed dimerization of resveratrol: a selective biomimetic synthesis

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Article information

DOI
https://doi.org/10.1039/C2GC36288K
Article type
Communication
Submitted
27 Jul 2012
Accepted
09 Oct 2012
First published
11 Oct 2012

Green Chem., 2012,14, 3281-3284

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pH-switched HRP-catalyzed dimerization of resveratrol: a selective biomimetic synthesis

C. Li, J. Lu, X. Xu, R. Hu and Y. Pan, Green Chem., 2012, 14, 3281 DOI: 10.1039/C2GC36288K

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