Volume 154, 2012

Electron solvation dynamics and reactivity in ionic liquids observed by picosecond radiolysis techniques

Abstract

On time scales of a nanosecond or less, radiolytically-generated excess electrons in ionic liquids undergo solvation processes and reactions that determine all subsequent chemistry and the accumulation of radiolytic damage. Using picosecond pulse radiolysis detection methods, we observed and quantified the solvation response of the electron in 1-methyl-1-butyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide and used it to understand electron scavenging by a typical solute, duroquinone.

Supplementary files

Article information

Article type
Paper
Submitted
13 Apr 2011
Accepted
01 Jun 2011
First published
13 Jul 2011

Faraday Discuss., 2012,154, 353-363

Electron solvation dynamics and reactivity in ionic liquids observed by picosecond radiolysis techniques

J. F. Wishart, A. M. Funston, T. Szreder, A. R. Cook and M. Gohdo, Faraday Discuss., 2012, 154, 353 DOI: 10.1039/C1FD00065A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements