Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]2+ core?

Emilie Lebon; Stéphanie Bastin; Pierre Sutra; Laure Vendier; Rémi E. Piau; Isabelle M. Dixon; Martial Boggio-Pasqua; Fabienne Alary; Jean-Louis Heully; Alain Igau; Alberto Juris

doi:10.1039/C1CC15737J

Can a functionalized phosphineligand promote room temperature luminescence of the [Ru(bpy)(tpy)]²⁺ core?†

Emilie Lebon,^a Stéphanie Bastin,^a Pierre Sutra,^a Laure Vendier,^a Rémi E. Piau,^b Isabelle M. Dixon,^b Martial Boggio-Pasqua,*^b Fabienne Alary,^b Jean-Louis Heully,^b Alain Igau*^a and Alberto Juris^c

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* Corresponding authors

^a Laboratoire de Chimie de Coordination, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex, France
E-mail: alain.igau@lcc-toulouse.fr
Fax: +33 561 55 30 03
Tel: +33 561 33 31 59

^b Laboratoire de Chimie et Physique Quantiques, UMR 5626, IRSAMC, CNRS et Université de Toulouse, Toulouse Cedex, France
E-mail: martial.boggio@irsamc.ups-tlse.fr
Fax: +33 561 55 60 65
Tel: +33 561 55 68 33

^c Dipartimento di Chimica “G. Ciamician”, Università di Bologna, via Selmi 2, 40126 Bologna, Italy

Abstract

Unexpected room temperature luminescence is observed and rationalized by highly challenging excited state calculations for a functionalized phosphine ligand coordinated on the [Ru(bpy)(tpy)]²⁺ core.

Chemical Communications

Can a functionalized phosphineligand promote room temperature luminescence of the [Ru(bpy)(tpy)]²⁺ core?†

Abstract

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Can a functionalized phosphine ligand promote room temperature luminescence of the [Ru(bpy)(tpy)]²⁺ core?

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