Issue 11, 2011

A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

Abstract

1H-Imidazo[4,5-f][1,10]phenanthroline (Hip) can be deprotonated to bridge Zn(II) ions, giving a flexible porous metal azolate framework [Zn7(ip)12](OH)2 (MAF-34) which shows not only drastic structural and luminescent changes for different solvent vapors, but also strong adsorption and quantitative luminescence response for low-pressure CO2.

Graphical abstract: A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

Supplementary files

Article information

Article type
Edge Article
Submitted
01 Jul 2011
Accepted
04 Aug 2011
First published
17 Aug 2011

Chem. Sci., 2011,2, 2214-2218

A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

X. Qi, R. Lin, Q. Chen, J. Lin, J. Zhang and X. Chen, Chem. Sci., 2011, 2, 2214 DOI: 10.1039/C1SC00421B

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