Issue 38, 2011
From the journal:

Chemical Communications

Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions†‡

Seiji Shirakawa,a   Shogo J. Terao,a   Rongjun Hea  and  Keiji Maruoka*a  

* Corresponding authors

a Laboratory of Synthetic Organic Chemistry and Special Laboratory of Organocatalytic Chemistry, Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: maruoka@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-4041
Tel: +81-75-753-4041

Abstract

Highly diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions was developed for the synthesis of α,α-disubstituted α-amino acid derivatives.

Graphical abstract: Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions

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Article information

DOI
https://doi.org/10.1039/C1CC14043D
Article type
Communication
Submitted
06 Jul 2011
Accepted
09 Aug 2011
First published
25 Aug 2011

Chem. Commun., 2011,47, 10557-10559

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Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions

S. Shirakawa, S. J. Terao, R. He and K. Maruoka, Chem. Commun., 2011, 47, 10557 DOI: 10.1039/C1CC14043D

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