Issue 15, 2011
From the journal:

Chemical Communications

High capacity gas storage by a 4,8-connected metal–organic polyhedral framework†‡

Chenrong Tan,a   Sihai Yang,a   Neil R. Champness,*a   Xiang Lin,a   Alexander J. Blake,a   William Lewisa  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK
E-mail: M.Schroder@nottingham.ac.uk, Neil.Champness@nottingham.ac.uk
Fax: +44 115 9513563
Tel: +44 1159513491

Abstract

The polyhedral complex [Cu4L(H2O)4]solv (NOTT-140) shows a 4,8-connected structure of rare scu topology comprising octahedral and cuboctahedral cages; desolvated NOTT-140a shows a total CO2 uptake of 314.6 cm3 (STP) cm−3 at 20 bar, 293 K, and a total H2 uptake of 6.0 wt% at 20 bar, 77 K.

Graphical abstract: High capacity gas storage by a 4,8-connected metal–organic polyhedral framework

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Article information

DOI
https://doi.org/10.1039/C1CC10378D
Article type
Communication
Submitted
20 Jan 2011
Accepted
02 Feb 2011
First published
11 Mar 2011

Chem. Commun., 2011,47, 4487-4489

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High capacity gas storage by a 4,8-connected metal–organic polyhedral framework

C. Tan, S. Yang, N. R. Champness, X. Lin, A. J. Blake, W. Lewis and M. Schröder, Chem. Commun., 2011, 47, 4487 DOI: 10.1039/C1CC10378D

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