Issue 10, 2011

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

Abstract

Impregnation of [(AliBu3)(Et2O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [([triple bond, length as m-dash]SiO)2Al(iBu)(Et2O)].

Graphical abstract: A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2010
Accepted
06 Jan 2011
First published
21 Jan 2011

Chem. Commun., 2011,47, 2979-2981

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

J. Pelletier, J. Espinas, N. Vu, S. Norsic, A. Baudouin, L. Delevoye, J. Trébosc, E. Le Roux, C. Santini, J. Basset, R. M. Gauvin and M. Taoufik, Chem. Commun., 2011, 47, 2979 DOI: 10.1039/C0CC04986G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements