Reversible hydrogen storage/release phenomena on lithium fulleride (LinC60) and their mechanistic investigation by solid-state NMR spectroscopy

Akihiro Yoshida; Takashi Okuyama; Tomoyuki Terada; Shuichi Naito

doi:10.1039/C1JM11542A

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Reversible hydrogen storage/release phenomena on lithium fulleride (Li_nC₆₀) and their mechanistic investigation by solid-state NMR spectroscopy†

Akihiro Yoshida,^a Takashi Okuyama,^a Tomoyuki Terada^a and Shuichi Naito*^a

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* Corresponding authors

^a Department of Material and Life Chemistry, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama, Japan
E-mail: naitos01@kanagawa-u.ac.jp

Abstract

The reversible hydrogen storage/release phenomena on a lithium–fullerene composite of lithium fulleride (Li_nC₆₀) were reported. NMR analyses revealed that LiH and C₆₀H_n were formed after hydrogen storage. Molecular hydrogen was stored as a proton (H⁺) incorporated with C₆₀ and a hydride (H⁻) incorporated with a Li ion.

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Article information

DOI: https://doi.org/10.1039/C1JM11542A
Article type: Communication
Submitted: 12 Apr 2011
Accepted: 05 May 2011
First published: 20 May 2011

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J. Mater. Chem., 2011,21, 9480-9482

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Reversible hydrogen storage/release phenomena on lithium fulleride (Li_nC₆₀) and their mechanistic investigation by solid-state NMR spectroscopy

A. Yoshida, T. Okuyama, T. Terada and S. Naito, J. Mater. Chem., 2011, 21, 9480 DOI: 10.1039/C1JM11542A

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Journal of Materials Chemistry