Issue 11, 2011
From the journal:

CrystEngComm

Two chiral tetradecanuclear hydroxo-lanthanide clusters with luminescent and magnetic properties†

Xi-Li Li,*a   Lai-Fu He,a   Xiang-Li Feng,a   You Song,*b   Min Hu,a   Li-Feng Han,a   Xian-Jun Zheng,a   Zhi-Hong Zhanga  and  Shao-Ming Fang*a  

* Corresponding authors

a Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou, China
E-mail: lixl@zzuli.edu.cn
Fax: +86 371 63556510

b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, China
E-mail: yousong@nju.edu.cn

Abstract

Two chiral tetradecanuclear hydroxo-lanthanide clusters of composition Ln14(µ4-OH)2(µ3-OH)16(µ-η2-acac)8(η2-acac)16·6H2O, where Ln = Dy 1, Tb 2 and acac = acetylacetonato, have been prepared and characterized by X-ray crystallographic, magnetic and spectroscopic methods. They crystallize in chiral monoclinic space group C2, which is exceptionally rare in hydroxo-lanthanide clusters, and present luminescent and magnetic properties.

Graphical abstract: Two chiral tetradecanuclear hydroxo-lanthanide clusters with luminescent and magnetic properties

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Article information

DOI
https://doi.org/10.1039/C0CE00826E
Article type
Communication
Submitted
08 Nov 2010
Accepted
09 Dec 2010
First published
05 Jan 2011

CrystEngComm, 2011,13, 3643-3645

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Two chiral tetradecanuclear hydroxo-lanthanide clusters with luminescent and magnetic properties

X. Li, L. He, X. Feng, Y. Song, M. Hu, L. Han, X. Zheng, Z. Zhang and S. Fang, CrystEngComm, 2011, 13, 3643 DOI: 10.1039/C0CE00826E

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