Issue 38, 2011
From the journal:

Chemical Communications

Early–late heterobimetallic Rh–Ti and Rh–Zr complexes via addition of early metal chlorides to mono- and divalent rhodium†

Dan A. Smitha  and  Oleg V. Ozerov*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, USA
E-mail: ozerov@chem.tamu.edu

Abstract

Addition of TiCl4 or ZrCl4 to (PNP)Rh(CH2[double bond, length as m-dash]CHtBu) (1) rapidly gives complexes (PNP)Rh(MCl3)(Cl) (M = Ti, 2; Zr, 3) in 75–77% yield (PNP = (4-Me-2-(iPr2P)–C6H3)2N). Compound 2 can also be synthesized via a reaction of (PNP)RhCl with TiCl3 or of (PNP)TiCl3 with 1/2 [(cod)RhCl]2.

Graphical abstract: Early–late heterobimetallic Rh–Ti and Rh–Zr complexes via addition of early metal chlorides to mono- and divalent rhodium

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Article information

DOI
https://doi.org/10.1039/C1CC14373E
Article type
Communication
Submitted
19 Jul 2011
Accepted
20 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 10779-10781

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Early–late heterobimetallic Rh–Ti and Rh–Zr complexes via addition of early metal chlorides to mono- and divalent rhodium

D. A. Smith and O. V. Ozerov, Chem. Commun., 2011, 47, 10779 DOI: 10.1039/C1CC14373E

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