Issue 44, 2011
From the journal:

Chemical Communications

Oxidative desulfurization of dibenzothiophene with hydrogen peroxide catalyzed by selenium(iv)-containing peroxotungstate†

Yiwen Hu,a   Qihui He,a   Zheng Zhang,a   Naidong Dinga  and  Baixing Hu*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Nanjing University, 22 Hankou Road, Nanjing, China
E-mail: hubx@nju.edu.cn
Fax: +86 25 83592878
Tel: +86 25 83592878

Abstract

With stoichiometric H2O2 as oxidant, dibenzothiophene (DBT) is oxidized to its corresponding sulfone with high efficiency, catalyzed by a sub-valence heteronuclear peroxotungstate, [C18H37N(CH3)3]4[H2SeIV3W6O34], under mild biphase conditions and the catalyst shows remarkable selectivity of catalytic oxidation towards DBT, cinnamyl alcohol and quinoline.

Graphical abstract: Oxidative desulfurization of dibenzothiophene with hydrogen peroxide catalyzed by selenium(iv)-containing peroxotungstate

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Article information

DOI
https://doi.org/10.1039/C1CC14153H
Article type
Communication
Submitted
11 Jul 2011
Accepted
23 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2011,47, 12194-12196

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Oxidative desulfurization of dibenzothiophene with hydrogen peroxide catalyzed by selenium(IV)-containing peroxotungstate

Y. Hu, Q. He, Z. Zhang, N. Ding and B. Hu, Chem. Commun., 2011, 47, 12194 DOI: 10.1039/C1CC14153H

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