Fine control of the N/S ratio and/or the position of the bridged heteroatoms in mixed heterocalix[4]arenes leads to a new approach to generate inherent chiral scaffolds and represents a new challenge to fine-tune cooperative properties.
![Graphical abstract: A new approach to inherent chirality through the N/S ratio and/or the position in mixed heterocalix[4]arenes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C1CC13390J&imageInfo.ImageIdentifier.Year=2011)
J. Raimundo, Z. Chen and O. Siri, Chem. Commun., 2011, 47, 10410 DOI: 10.1039/C1CC13390J
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