Issue 25, 2011
From the journal:

Chemical Communications

Volatilisation of ferrocene from ionic liquids: kinetics and mechanism†

Chaopeng Fu,a   Leigh Aldous,a   Edmund J. F. Dickinson,a   Ninie S. A. Mananbc  and  Richard G. Compton*a  

* Corresponding authors

a Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK
E-mail: Richard.compton@chem.ox.ac.uk

b School of Chemistry and Chemical Engineering, The QUILL Centre, Queen's University Belfast, Belfast BT9 5AG, UK

c Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

Abstract

The evaporation of dissolved ferrocene from non-volatile ionic liquids under a flow of nitrogen gas has been monitored voltammetrically and modelled mathematically. The rate of volatilisation was found to depend on the surface tension of the ionic liquid, and a model is presented.

Graphical abstract: Volatilisation of ferrocene from ionic liquids: kinetics and mechanism

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Article information

DOI
https://doi.org/10.1039/C1CC12336J
Article type
Communication
Submitted
21 Apr 2011
Accepted
11 May 2011
First published
24 May 2011

Chem. Commun., 2011,47, 7083-7085

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Volatilisation of ferrocene from ionic liquids: kinetics and mechanism

C. Fu, L. Aldous, E. J. F. Dickinson, N. S. A. Manan and R. G. Compton, Chem. Commun., 2011, 47, 7083 DOI: 10.1039/C1CC12336J

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