Issue 24, 2011
From the journal:

Chemical Communications

A linear single-molecule magnet based on [RuIII(CN)6]3−†

Kasper S. Pedersen,*a   Jan Dreiser,*b   Joscha Nehrkorn,c   Maren Gysler,c   Magnus Schau-Magnussen,a   Alexander Schnegg,d   Karsten Holldack,e   Robert Bittl,f   Stergios Piligkos,a   Høgni Weihe,a   Philip Tregenna-Piggott,‡g   Oliver Waldmann*c  and  Jesper Bendix*a  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen, Denmark
E-mail: ksp@kiku.dk, bendix@kiku.dk
Tel: +45 353 20112

b Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland
E-mail: jan.dreiser@psi.ch

c Physikalisches Institut, Universität Freiburg, D-79104 Freiburg, Germany
E-mail: oliver.waldmann@physik.uni-freiburg.de

d Institut für Silizium-Photovoltaik, Helmholtz-Zentrum Berlin, D-12489 Berlin, Germany

e Institut für Methoden und Instrumente der Forschung mit Synchrotronstrahlung, Helmholtz-Zentrum Berlin, D-12489 Berlin, Germany

f Institut für Physik, Freie Universität Berlin, D-10115 Berlin, Germany

g Laboratory for Neutron Scattering, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland

Abstract

We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [RuIII(CN)6]3−. Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn–Ru exchange interactions.

Graphical abstract: A linear single-molecule magnet based on [RuIII(CN)6]3−

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Article information

DOI
https://doi.org/10.1039/C1CC12158H
Article type
Communication
Submitted
14 Apr 2011
Accepted
27 Apr 2011
First published
20 May 2011

Chem. Commun., 2011,47, 6918-6920

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A linear single-molecule magnet based on [RuIII(CN)6]3−

K. S. Pedersen, J. Dreiser, J. Nehrkorn, M. Gysler, M. Schau-Magnussen, A. Schnegg, K. Holldack, R. Bittl, S. Piligkos, H. Weihe, P. Tregenna-Piggott, O. Waldmann and J. Bendix, Chem. Commun., 2011, 47, 6918 DOI: 10.1039/C1CC12158H

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