First isolation of fully delocalized mixed-valent imido-bridged [Ti2]7+ complexes by one-electron reduction of [(C5R5)TiCl]2(μ-NAr)2†
Abstract
Mixed-valent imido-bridged dinuclear titanium complexes, [Cp2Co][{(C5R5)TiCl}2(μ-NAr)2] (R = H, Me; Ar = 3,5-(CF3)2C6H3), were prepared by one-electron