Irreversible solvent-driven conversion in cyanometalate {Fe2Ni}n (n = 2, 3) single-molecule magnets

Yuan-Zhu Zhang; Uma P. Mallik; Rodolphe Clérac; Nigam P. Rath; Stephen M. Holmes

doi:10.1039/C1CC10679A

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Irreversible solvent-driven conversion in cyanometalate {Fe₂Ni}_n (n = 2, 3) single-molecule magnets†

Yuan-Zhu Zhang,^a Uma P. Mallik,^a Rodolphe Clérac,*^bc Nigam P. Rath^a and Stephen M. Holmes*^ad

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* Corresponding authors

^a Department of Chemistry and Biochemistry, University of Missouri-St. Louis, St. Louis, Missouri 63121, USA
E-mail: holmesst@umsl.edu
Fax: (+1) 314 516 5342
Tel: (+1) 314 516 4382

^b CNRS, UPR 8641, Centre de Recherche Paul Pascal (CRPP), Equipe “Matériaux Moléculaires Magnétiques”, 115 avenue du Dr Albert Schweitzer, Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr
Fax: (+33) 5 56 84 56 00
Tel: (+33) 5 56 84 56 50

^c Université de Bordeaux, UPR 8641, Pessac, France

^d Center for Nanoscience, University of Missouri-St. Louis, St. Louis, Missouri 63121, USA

Abstract

Two cyano-bridged single-molecule magnets of {Fe^III₄Ni^II₂} and {Fe^III₆Ni^II₃} stoichiometry are described via their magnetic properties described in the frame of geometrical core distortions and orientations of their local anisotropy axes.

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Article information

DOI: https://doi.org/10.1039/C1CC10679A
Article type: Communication
Submitted: 03 Feb 2011
Accepted: 28 Apr 2011
First published: 31 May 2011

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Chem. Commun., 2011,47, 7194-7196

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Irreversible solvent-driven conversion in cyanometalate {Fe₂Ni}_n (n = 2, 3) single-molecule magnets

Y. Zhang, U. P. Mallik, R. Clérac, N. P. Rath and S. M. Holmes, Chem. Commun., 2011, 47, 7194 DOI: 10.1039/C1CC10679A

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