We present a fundamental method to assess the doping limits of hetero-polar materials; applied to the case of ZnO, we show clearly that electrons are stable and holes are unstable under the limits of thermodynamic control.
C. R. A. Catlow, A. A. Sokol and A. Walsh, Chem. Commun., 2011, 47, 3386 DOI: 10.1039/C1CC10314H
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