Issue 46, 2010
From the journal:

Chemical Communications

Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”†

Wenge Qiu,ab   Jason A. Perman,a   Łukasz Wojtas,a   Mohamed Eddaoudia  and  Michael J. Zaworotko*a  

* Corresponding authors

a Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, Florida, USA
E-mail: xtal@usf.edu
Tel: +1 813-974-3451

b Department of Chemical Science and Engineering, College of Environmental and Engineering, Beijing University of Technology, Beijing, China
E-mail: qiuwenge@bjut.edu.cn
Fax: +86 10-67391983
Tel: +86 10-67396588

Abstract

Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagomé lattices of formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.

Graphical abstract: Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

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Article information

DOI
https://doi.org/10.1039/C0CC03270K
Article type
Communication
Submitted
15 Aug 2010
Accepted
22 Sep 2010
First published
22 Oct 2010

Chem. Commun., 2010,46, 8734-8736

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Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

W. Qiu, J. A. Perman, Ł. Wojtas, M. Eddaoudi and M. J. Zaworotko, Chem. Commun., 2010, 46, 8734 DOI: 10.1039/C0CC03270K

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