Issue 28, 2010
From the journal:

Chemical Communications

Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(iv) oxidenanocrystals in the presence of dissolved sodium hydroxide†

Kojirou Fuku,a   Keiji Hashimotoa  and  Hiroshi Kominami*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashiosaka, Osaka 577-8502, Japan
E-mail: hiro@apch.kindai.ac.jp
Fax: +81-6-6727-2024
Tel: +81-6-6721-2332

Abstract

Photocatalytic reaction of chlorobenzene in 2-propanol suspension of palladium- and rhodium-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide under deaerated conditions, in which 2-propanol, metal loaded (palladium and rhodium) and sodium hydroxide effectively acted as hole scavenger, co-catalyst and chloride solidifier, respectively, quantitatively gave benzene and chloride ions with a high stoichiometry.

Graphical abstract: Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(iv) oxide nanocrystals in the presence of dissolved sodium hydroxide

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Article information

DOI
https://doi.org/10.1039/C0CC00589D
Article type
Communication
Submitted
25 Mar 2010
Accepted
18 May 2010
First published
11 Jun 2010

Chem. Commun., 2010,46, 5118-5120

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Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide

K. Fuku, K. Hashimoto and H. Kominami, Chem. Commun., 2010, 46, 5118 DOI: 10.1039/C0CC00589D

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