On the tuning of electric conductance of extended metal atom chains via axial ligands for [Ru3(μ3-dpa)4(X)2]0/+ (X = NCS−, CN−)

Kai-Neng Shih; Min-Jie Huang; Hao-Cheng Lu; Ming-Dung Fu; Ching-Kuo Kuo; Gin-Chen Huang; Gene-Hsiang Lee; Chun-hsien Chen; Shie-Ming Peng

doi:10.1039/B916677G

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On the tuning of electric conductance of extended metal atom chains via axial ligands for [Ru₃(μ₃-dpa)₄(X)₂]⁰^/+ (X = NCS⁻, CN⁻)†

Kai-Neng Shih,‡^a Min-Jie Huang,‡^a Hao-Cheng Lu,^a Ming-Dung Fu,^b Ching-Kuo Kuo,^a Gin-Chen Huang,^a Gene-Hsiang Lee,^a Chun-hsien Chen*^a and Shie-Ming Peng*^a

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* Corresponding authors

^a Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan, ROC
E-mail: chhchen@ntu.edu.tw, smpeng@ntu.edu.tw

^b Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC

Abstract

The influence of a π-acid cyanide axial ligand on the metal–metal interactions of [Ru₃(μ₃-dpa)₄(X)₂]⁰^/+ (X = NCS⁻, CN⁻) is manifested by the measurements of single-molecule conductance coupled with in situ electrochemical control.

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Article information

DOI: https://doi.org/10.1039/B916677G
Article type: Communication
Submitted: 13 Aug 2009
Accepted: 09 Dec 2009
First published: 08 Jan 2010

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Chem. Commun., 2010,46, 1338-1340

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On the tuning of electric conductance of extended metal atom chains via axial ligands for [Ru₃(μ₃-dpa)₄(X)₂]⁰^/+ (X = NCS⁻, CN⁻)

K. Shih, M. Huang, H. Lu, M. Fu, C. Kuo, G. Huang, G. Lee, C. Chen and S. Peng, Chem. Commun., 2010, 46, 1338 DOI: 10.1039/B916677G

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