Issue 28, 2010
From the journal:

Dalton Transactions

A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis†

Matthew S. Jeletic,a   Ion Ghiviriga,a   Khalil A. Abbouda  and  Adam S. Veige*a  

* Corresponding authors

a Center for Catalysis, Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, Florida, USA
E-mail: veige@chem.ufl.edu
Fax: 352-392-9844
Tel: 352-392-9844

Abstract

This report details the synthesis and characterization of the first chiral diNHC cyclophane ligand and its palladium allyl complex. The complex was tested for 1,4-conjugate addition of phenylboronic acid to 2-cyclohexen-1-one and provides R-3-phenylcyclohexanone in 50% enantiomeric excess.

Graphical abstract: A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis

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Article information

DOI
https://doi.org/10.1039/C0DT00268B
Article type
Communication
Submitted
06 Apr 2010
Accepted
25 May 2010
First published
21 Jun 2010

Dalton Trans., 2010,39, 6392-6394

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A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis

M. S. Jeletic, I. Ghiviriga, K. A. Abboud and A. S. Veige, Dalton Trans., 2010, 39, 6392 DOI: 10.1039/C0DT00268B

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