Issue 11, 2010
From the journal:

CrystEngComm

A spontaneously resoluted zinc–organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand†‡

Xiao-Qiang Liang,a   Jiang-Tao Jia,a   Tao Wu,b   Dong-Ping Li,b   Lei Liu,a   Tsolmona  and  Guang-Shan Zhu*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, China
E-mail: zhugs@mail.jlu.edu.cn
Fax: +86 431 85168331
Tel: +86 431 85168887

b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, China

Abstract

A homochiral 3D diamondoid metal–organic framework [Zn2(etza)4] (1, named JUC-81, JUC = Jilin University, China, Hetza = ethyl 1H-tetrazole-5-acetate) has been prepared through spontaneous resolution. The bulk crystals have enantiomeric excess observed by vibrational circular dichroism (VCD) spectra, and also show second-order nonlinear optical effects and ferroelectric feature.

Graphical abstract: A spontaneously resoluted zinc–organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CE00329H
Article type
Communication
Submitted
03 May 2010
Accepted
25 Jun 2010
First published
30 Jul 2010

CrystEngComm, 2010,12, 3499-3501

Permissions

Request permissions

A spontaneously resoluted zinc–organic framework with nonlinear optical and ferroelectric properties generated from tetrazolate-ethyl ester ligand

X. Liang, J. Jia, T. Wu, D. Li, L. Liu, Tsolmon and G. Zhu, CrystEngComm, 2010, 12, 3499 DOI: 10.1039/C0CE00329H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements