Issue 42, 2010
From the journal:

Chemical Communications

Effect of anion binding on charge stabilization in a bis-fullerene–oxoporphyrinogen conjugate†‡

Jonathan P. Hill,*ab   Mohamed E. El-Khouly,c   Richard Charvet,a   Navaneetha K. Subbaiyan,d   Katsuhiko Ariga,ab   Shunichi Fukuzumi*ce  and  Francis D'Souza*d  

* Corresponding authors

a WPI-Center for Materials Nanoarchitectonics, National Institute of Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki, Japan
E-mail: Jonathan.Hill@nims.go.jp

b JST-CREST, Namiki 1-1, Tsukuba, Japan

c Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: Fukuzumi@chem.eng.osaka.u.ac.jp
Tel: +81-6-6879-7368

d Department of Chemistry, Wichita State University, 1845, Fairmount, Wichita, USA
E-mail: Francis.DSouza@Wichita.edu
Tel: 316-878-3431

e Department of Bioinspired Science, Ewha Womans University, Seoul, Korea

Abstract

Presence of strongly binding anion, F− stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.

Graphical abstract: Effect of anion binding on charge stabilization in a bis-fullerene–oxoporphyrinogen conjugate

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC03167D
Article type
Communication
Submitted
10 Aug 2010
Accepted
06 Sep 2010
First published
22 Sep 2010

Chem. Commun., 2010,46, 7933-7935

Permissions

Request permissions

Effect of anion binding on charge stabilization in a bis-fullerene–oxoporphyrinogen conjugate

J. P. Hill, M. E. El-Khouly, R. Charvet, N. K. Subbaiyan, K. Ariga, S. Fukuzumi and F. D'Souza, Chem. Commun., 2010, 46, 7933 DOI: 10.1039/C0CC03167D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements