Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

Xiao-Lan Tong; Tong-Liang Hu; Jiong-Peng Zhao; Yue-Kui Wang; Hui Zhang; Xian-He Bu

doi:10.1039/C0CC03111A

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Chiral magnetic metal–organic frameworks of Mn^II with achiral tetrazolate-based ligands by spontaneous resolution†

Xiao-Lan Tong,^a Tong-Liang Hu,^a Jiong-Peng Zhao,^a Yue-Kui Wang,^b Hui Zhang^c and Xian-He Bu*^a

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* Corresponding authors

^a Department of Chemistry, and Tianjin Key Lab on Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458

^b Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

^c Department of Chemistry, Xiamen University, Xiamen 363105, China

Abstract

The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.

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Article information

DOI: https://doi.org/10.1039/C0CC03111A
Article type: Communication
Submitted: 07 Aug 2010
Accepted: 20 Sep 2010
First published: 19 Oct 2010

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Chem. Commun., 2010,46, 8543-8545

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Chiral magnetic metal–organic frameworks of Mn^II with achiral tetrazolate-based ligands by spontaneous resolution

X. Tong, T. Hu, J. Zhao, Y. Wang, H. Zhang and X. Bu, Chem. Commun., 2010, 46, 8543 DOI: 10.1039/C0CC03111A

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