Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface

Simon Tricard; Benoit Fleury; Florence Volatron; Claire Costa-Coquelard; Sandra Mazerat; Vincent Huc; Christophe David; François Brisset; Frédéric Miserque; Pascale Jegou; Serge Palacin; Talal Mallah

doi:10.1039/C003039B

Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface†

Simon Tricard,^a Benoit Fleury,^a Florence Volatron,^a Claire Costa-Coquelard,^a Sandra Mazerat,^a Vincent Huc,^a Christophe David,^b François Brisset,^a Frédéric Miserque,^c Pascale Jegou,^d Serge Palacin^d and Talal Mallah*^a

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^a Institut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris 11, 91405 Orsay, France
E-mail: talal.mallah@u-psud.fr
Fax: +33169144754
Tel: +33169144749

^b Laboratoire de Photonique et de Nanostructures, CNRS, route de Nozay, 91460 Marcoussis, France

^c CEA-Saclay/DEN/DANS/DPC/SCP/LRSI, Bât 391, 91191 Gif-sur-Yvette cedex, France

^d Chimie des Surfaces et Interfaces, CEA/DRECAM, CEA-Saclay, 91191 Gif sur Yvette, France

Abstract

Isolated nanometric objects of the nickel–iron cyanide-bridged coordination network are obtained by a sequential growth on “molecular seeds” anchored on Si(100) surfaces. Control of the density and the size of the nano-objects is achieved by imposing a growth process without side nucleation.

Chemical Communications

Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface†

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Growth and density control of nanometric nickel–iron cyanide-bridged objects on functionalized Si(100) surface

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