Issue 17, 2010
From the journal:

Chemical Communications

Rapid access to 1-methyleneindenes viapalladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzenes with arylboronic acids†‡

Shengqing Ye,a   Xiaodi Yangc  and  Jie Wu*ab  

* Corresponding authors

a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China
E-mail: jie_wu@fudan.edu.cn
Fax: 86 21 6564 1740
Tel: 86 21 6510 2412

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, China

c Laboratory of Advanced Materials, Fudan University, 220 Handan Road, Shanghai 200433, China

Abstract

A novel and efficient route for the synthesis of 1-methyleneindenes via palladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzene with arylboronic acids is described. This reaction proceeded under mild conditions with high efficiency and excellent selectivity.

Graphical abstract: Rapid access to 1-methyleneindenes via palladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzenes with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/B926763H
Article type
Communication
Submitted
18 Dec 2009
Accepted
13 Feb 2010
First published
08 Mar 2010

Chem. Commun., 2010,46, 2950-2952

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Rapid access to 1-methyleneindenes via palladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzenes with arylboronic acids

S. Ye, X. Yang and J. Wu, Chem. Commun., 2010, 46, 2950 DOI: 10.1039/B926763H

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