Issue 21, 2009
From the journal:

Dalton Transactions

Stabilisation of a very short Cu–F bond within the protected cavity of a copper(ii) compound from a tris(2-aminoethyl)amine derivative†

Ann Almesåker,ab   Patrick Gamez,b   Jan Reedijk,*b   Janet L. Scott,a   Leone Spiccia*a  and  Simon J. Teatc  

* Corresponding authors

a School of Chemistry and Centre for Green Chemistry, Monash University, Victoria, Australia
E-mail: leone.spiccia@monash.edu.au.
Fax: +61 3 9905 4597
Tel: +61 3 9905 4526

b Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, Leiden, RA, The Netherlands
E-mail: reedijk@chem.leidenuniv.nl.
Fax: +31 71 527 4671
Tel: +31 71 527 4459

c Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California, USA

Abstract

The copper(II) coordination compound of an N-functionalised derivative of tris(2-aminoethyl)amine forms a cavity that is an excellent fluoride ion host, generating a Cu–F entity with a very short distance (182 pm) and characterised by a fluoride ion devoid of any additional intermolecular interactions.

Graphical abstract: Stabilisation of a very short Cu–F bond within the protected cavity of a copper(ii) compound from a tris(2-aminoethyl)amine derivative

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Article information

DOI
https://doi.org/10.1039/B902907A
Article type
Communication
Submitted
11 Feb 2009
Accepted
26 Mar 2009
First published
08 Apr 2009

Dalton Trans., 2009, 4077-4080

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Stabilisation of a very short Cu–F bond within the protected cavity of a copper(II) compound from a tris(2-aminoethyl)amine derivative

A. Almesåker, P. Gamez, J. Reedijk, J. L. Scott, L. Spiccia and S. J. Teat, Dalton Trans., 2009, 4077 DOI: 10.1039/B902907A

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