Issue 8, 2009
From the journal:

Dalton Transactions

Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks†

Frédérick Dorson,a   Yann Molard,*a   Stéphane Cordier,*a   Bruno Fabre,a   Olga Efremova,b   David Rondeau,c   Yuri Mironov,b   Viorel Cîrcu,d   Nikolay Naumovb  and  Christiane Perrina  

* Corresponding authors

a Sciences Chimiques de Rennes UMR 6226 CNRS Université de Rennes 1, Avenue du Général Leclerc, Rennes Cedex, France
E-mail: yann.molard@univ-rennes1.fr, stephane.cordier@univ-rennes1.fr
Fax: +33 (0)2323 6536
Tel: +33 (0)223 235 814

b Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3 Acad. Lavrentiev pr., Novosibirsk, Russia

c CIMA CNRS 6200, Université d'Angers, 2 Bd. Lavoisier, Angers, France

d Department of Inorganic Chemistry, University of Bucharest, Dumbrava Rosie 23, Bucharest, 020464, sector 2, Romania

Abstract

The reaction of [Re6Qi8(OH)a6]4− (Q = S, Se) with p-tert-butylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.

Graphical abstract: Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

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Article information

DOI
https://doi.org/10.1039/B822105G
Article type
Communication
Submitted
09 Dec 2008
Accepted
08 Jan 2009
First published
21 Jan 2009

Dalton Trans., 2009, 1297-1299

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Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4− (Q = S, Se) to neutral trans-[Re6Q8L4L′2] hybrid building blocks

F. Dorson, Y. Molard, S. Cordier, B. Fabre, O. Efremova, D. Rondeau, Y. Mironov, V. Cîrcu, N. Naumov and C. Perrin, Dalton Trans., 2009, 1297 DOI: 10.1039/B822105G

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