Issue 35, 2009
From the journal:

Dalton Transactions

Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes†

Slawomir Urban,a   Matyas Tursky,ab   Roland Fröhlicha  and  Frank Glorius*a  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, Münster, Germany
E-mail: glorius@uni-muenster.de
Fax: +49 251-8333202

b Department of Chemistry, Technical University of Denmark, Building 201, 2800 Kgs., Lyngby, Denmark

Abstract

The investigation of the electronic and steric properties of 4,5-disubstituted imidazolylidenes is reported, as well as their successful application as organocatalysts in the formation of γ-butyrolactones by conjugate Umpolung.

Graphical abstract: Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/B908981K
Article type
Communication
Submitted
06 May 2009
Accepted
08 Jul 2009
First published
17 Jul 2009

Dalton Trans., 2009, 6934-6940

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Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes

S. Urban, M. Tursky, R. Fröhlich and F. Glorius, Dalton Trans., 2009, 6934 DOI: 10.1039/B908981K

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